校内邮箱

科研成果    
  研究方向  
  科研成果  
  教学成果  

当前位置: 科学研究 科研成果
2015年龙8游戏手机网页版登录代表性文章
阅读次数:5276 添加时间:2015/6/23 发布: 管理员
【字体: 字体颜色

 

 

 

1.        C. Xiao, X. M. Ren* et al.,‘Integrated, highly crystalline and water stable coordination framework film on various substrates and water-assisted protonic conductivity’, Chem. Commun. 2015, 51, 7947-7949.

链接:http://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc02392k

The integrated, highly crystalline and water stable Prussian blue analogue films were successfully fabricated on the porous a-Al2O3, the conducting ITO and the flexible non-woven fabric substrates,respectively, using the self-assembly approach. The proton conduction was investigated for both powdered pellets and the film on the

porous a-Al2O3 substrate. This study promotes the practical applications of MOF-based proton conductors in various devices.

2.        X. P. Li, X. M. Ren* et al.,‘Investigation of structure and ionic conductivity for intercalated kaolinites with potassium acetate in hydrous and anhydrous phases’, Dalton Trans. 2015, 44, 4665-4670.

链接:http://pubs.rsc.org/en/content/articlelanding/2015/dt/c4dt04018j

The intercalated kaolinite with potassium acetate (K-KAc), with ca. 91.9% intercalation ratio, was prepared. Thermogravimetric and variable-temperature X-ray powder diffraction analyses disclosed that a small amount of water is easily absorbed into the interlayer space of the K-KAc. The previously reported phase with the 14.2 ? interlayer distance is actually the hydrous K-KAc, which has an approximate formula of Al2Si2O5(OH)4·0.5KAc·0.25H2O. The crystal structures of hydrous and anhydrous phases of K-KAc were simulated in the density functional theory framework, demonstrating that the interactions between the K+ and acetate ions and the inner surface of kaolinite are significantly strengthened in the anhydrous phase with regard to the hydrous phase. The ionic conductivity of K-KAc indicated that the mobility of the interlayer ions is strongly improved by thermal activation and the conductivity increased by four orders of magnitude from 363 to 423 K.

3.        Halogen-substituted imidazoline derivatives as corrosion inhibitors for mild steel in hydrochloric acid solution

Kegui Zhang(张可桂), Bin Xu(徐斌), Wenzhong Yang(杨文忠), Xiaoshuang Yin(尹晓爽), Ying Liu(刘瑛), Yizhong Chen(陈毅中).

Corrosion Science, 2015, 90: 284-295

链接:http://www.sciencedirect.com/science/article/pii/S0010938X14004892

该报道以卤代乙酸和二乙烯三胺为原料,首次合成出两种卤代咪唑啉化合物,并通过静态失重法、动电位极化曲线、电化学阻抗和量子化学等方法评价了该类物质在盐酸介质中对碳钢的缓蚀性能。该研究对咪唑啉类缓蚀剂的理论发展和实际生产均有一定的指导意义。

4.        Corrosion inhibition of mild steel by bromide-substituted imidazoline in hydrochloric acid

Kegui Zhang(张可桂), Wenzhong Yang(杨文忠), Bin Xu(徐斌), Ying Liu(刘瑛), Xiaoshuang Yin(尹晓爽), Yizhong Chen(陈毅忠).

Journal of the Taiwan Institute of Chemical Engineers, 2015.article in press

链接:http://www.sciencedirect.com/science/article/pii/S1876107015001790

该报道选用三溴乙酸和二乙烯三胺为原料,将溴元素引入到咪唑啉化合物中,并通过实验方法对该化合物在盐酸溶液中对Q235钢腐蚀的抑制作用进行评价。此研究完善了卤代咪唑啉缓蚀剂体系(FClBr),并通过量子化学和分子动态模拟探究卤素基团对化合物缓蚀性能的影响规律。

5.        Narrow-disperse, Highly Cross-Linked, and “Living” PolymerMicrospheres by Two-Stage Precipitation Polymerization

Ying Liu(刘瑛), Di Wu(吴迪), Kun Zhang(张坤), Xiaoshuang Yin(尹晓爽), Wenzhong Yang(杨文忠)

Chinese Journal of Polymer Science, 2015, (article in press)

链接:http://www.cjps.org/CN/abstract/abstract12904.shtml

6.        Multichannel detection of Cu2+ based on a rhodamine-ethynylferrocene conjugate

XingWen Cheng(成杏文),Yi Zhou(周翼)*, Yuan Fang(方园),QingQing Rui(芮清清), Cheng Yao(姚成)*

RSC Advances, 2015, 5, 19465-19469 (IF = 3.708)

链接:http://pubs.rsc.org/en/Content/ArticleLanding/2015/RA/c5ra00152h#!divAbstract

该报道基于二茂铁修饰四甲基罗丹明母体构筑了一例对Cu2+具有色度、荧光、电化学多通道信号相应的识别探针。该探针在多种金属离子存在,宽泛的pH条件下对Cu2+均表现出了良好的选择性及亲和性。

7.        Naphthalimide-Rhodamine based chemosensors for colorimetric and fluorescent sensing Hg2+ through different signaling mechanisms in corresponding solvent systems

Yuan Fang(方园), Yi Zhou(周翼)*, Ju-Ying Li(李菊影), Qing-Qing Rui(芮清清), Cheng Yao(姚成)*

Sensors and Actuators B: Chemical, 2015, 215, 350-359 (IF = 3.840)

链接:http://www.sciencedirect.com/science/article/pii/S092540051500413X

该报道将1,8-萘酰亚胺通过乙二胺分别引入罗丹明6G及罗丹明B荧光母体,构筑了两例对Hg2+具有色度及荧光响应的选择性探针。基于溶剂环境的不同,两例探针对于Hg2+表现出了不同的识别机理及信号相应。

8.        Hai Huang, Xiaolin Zhu, Guangke He, Qi Liu, Junzhen Fan, and Hongjun Zhu, Controlled Synthesis of 1,3,5-Oxadiazin-2-ones and Oxazolones through Regioselective Iodocyclization of Ynamides [J], Org. Lett. 2015, 17, 2510-2513.

网站链接

http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b01045?journalCode=orlef7&quickLinkVolume=17&quickLinkPage=2510&selectedTab=citation&volume=17

简介:

环状氨基甲酸酯类化合物由于其独特的生物活性备受研究人员的广泛关注。朱红军教授课题组使用NISN-碘代丁二酰亚胺)作为亲电试剂,以炔酰胺为底物,在室温及氮气条件下,通过反应条件的调控实现了1,3,5-二嗪-2-酮和唑-2-酮的选择性合成。两类反应条件温和,具有良好的官能团兼容性。并且由该方法合成的系列碘代产物易发生后续Heck, Suzuki, Sonogashira等偶联反应,为更多新型分子的构建提供了具有潜力的先导物。

9.        Hai Huang, Guangke He, Guohao Zhu, Xiaolin Zhu, Shineng Qiu, and Hongjun Zhu, Palladium-Catalyzed Intramolecular Cyclization of Ynamides: Synthesis of 4?Halo-oxazolones [J], J. Org. Chem. 2015, 80, 3480-3487.

网站链接

http://pubs.acs.org/doi/abs/10.1021/acs.joc.5b00071?journalCode=joceah&quickLinkVolume=80&quickLinkPage=3480&selectedTab=citation&volume=80

简介:

-2-酮类化合物由于其独特的生物活性备受研究人员的广泛关注。朱红军教授课题组首次利用卤钯化学催化体系,以炔酰胺为底物,在较为温和的条件下,实现了4-卤代唑-2-酮的快速高效合成。该反应时间小于40min,并且具有良好的官能团兼容性。并且由该方法合成的系列卤代产物易发生后续Suzuki等把催化偶联反应,为更多新型分子的构建提供了具有潜力的先导物。

10.    Copper-catalyzed trifluoromethylation of organic zinc reagents with an electrophilic trifluoromethylating reagent

Chang-Sheng Wang(王昌盛), Haoyang Wang(王昊阳), Cheng Yao(姚成)*

RSC Advances, 2015, 5, 24783-24787 (IF = 3.708)

链接:http://pubs.rsc.org/en/Content/ArticleLanding/2015/RA/c5ra02279g#!divAbstract

该报道介绍了在Togni试剂存在条件下,利用铜催化芳基、乙烯基、烷基锌试剂的三氟甲基化反应。机理研究表明,芳基被从锌试剂转移到高价碘,从而以形成一个三取代高价碘中间体。还原消除反应经由该中间体通过键形成、自由基途径从而生成三氟甲基化芳烃。

(相关研究工作还发表于Organic Letters, 2014, 16, 5544-5547 (IF = 6.324),

11.    Kai Chen, Qi Liu, Jue-Ping Ni, Hong-Jun Zhu,* Yu-Feng Li, and Qiang Wang, Synthesis, insecticidal activities and structureactivity relationship studies of novel anthranilic diamides containing pyridylpyrazole-4-carboxamide [J], Pest Management Science, 2015, DOI: 10.1002/ps.3243

网站链接

http://onlinelibrary.wiley.com/doi/10.1002/ps.3243/abstract

简介

吡唑甲酰胺类化合物由于具有酰胺和吡唑两个高活性基团,从而具有广泛的生物活性。本文以邻氨基苯甲酰胺结构为母体,引入吡啶基吡唑-4-甲酰胺,从而设计合成一类新型邻氨基苯甲酰胺类化合物,并对其进行了生物活性测试及构效关系的研究。生物活性测试结果表明大多数化合物在100 mg L?1浓度下对小菜蛾表现出90 %以上的杀虫活性。此外,本文通过密度泛函理论研究发现,前线分子轨道的研究对构效关系的解释具有指导意义。

12.    Study on physicochemical and in-vitro enzymatic hydrolysis properties of ginkgo (Ginkgo biloba) starch

Yi Zheng(郑义), Huanxin Zhang(张焕新)*, Cheng Yao(姚成)*, Lanlan Hu(胡兰兰), Yujiao Peng(彭玉娇), Jie Shen(沈杰)

Food Hydrocolloids, 2015, 48, 312-319 (IF = 4.280)

链接:http://www.sciencedirect.com/science/article/pii/S0268005X15001083

该报道介绍了银杏种子中直链淀粉的几种分离方法。并对淀粉的组成、物理化学性质、结构特征进行了表征分析。银杏淀粉是酶抗性淀粉一个强大的和潜在的有用营养源,研究结果提供了在食品工业中使用银杏种子的有用信息。

13.    Rhodamine-Ferrocene Conjugate Chemosensor for Selectively Sensing Copper(II) with Multisignals: Chromaticity, Fluorescence, and Electrochemistry and Its Application in Living Cell Imaging

Yuan Fang(方园),Yi Zhou(周翼)*, Qingqing Rui(芮清清), Cheng Yao(姚成)*

Organometallics, 2015, DOI: 10.1021 / acs.organomet.5b00285 (IF = 4.253)

链接:http://pubs.acs.org/doi/abs/10.1021/acs.organomet.5b00285

该报道通过炔基将二茂铁引入水杨醛罗大明6G腙荧光母体构筑了一例对于Cu2+具有色度、荧光、电化学多通道相应的选择性探针。并实现了在纯水体系中Cu2+的检测及HeLa细胞内Cu2+的成像研究。

14.    An electrochemical sensing strategy based on a three dimensional ordered macroporous polyanilineplatinum platform and a mercury(II) ion-mediated DNAzyme functionalized nanolabel

Rong Tian(田荣), Xiaojun Chen(陈晓君)*, Nan Jiang(蒋楠), Ning Hao(郝宁), Lin Xu(徐琳), Cheng Yao (姚成)*

Journal of Materials Chemistry B, 2015, 3, 4805-4813 (IF = Pending)

链接:http://pubs.rsc.org/en/Content/ArticleLanding/2015/TB/C5TB00796H#!divAbstract

本报道基于三维有序大孔聚苯胺 - 铂(3DOM PANI-Pt)的复合膜,设计了一例对于Hg2+具有高度敏感性的DNA生物电化学探针。该探针的检出限低于已有报道的DNA探针,并能成功应用于实际水样中Hg2+的检测。

15.    Site-selective recognition of peptide phosphorylation by a terbium(III) complex in aqueous solution

Xiaohui Wang(王晓辉)*, Tao Yang(杨桃), Jian Luo*(罗剑), Liu Yang(杨柳), Cheng Yao(姚成)*

Chemical Communications, 2015, 51, 8185-8188 (IF = 6.718)

链接:http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC01056J#!divAbstract

该报道介绍了一例对磷酸化多肽具有高效选择性的铽(III)配合物探针。在有锌离子共存的条件下,通过荧光增强信号响应成功地将其应用于缓冲溶液及小鼠脑浆蛋白提取液体系中磷酸化多肽的检测。

   

A facile approach has been developed to obtain narrow-disperse surface-functionalized, cross-linked “living” polymer microspheres by two-stage precipitation technique. Narrow-disperse polymer microspheres with their size ranging from 0.95 μm to 2.36 μm were readily prepared and the size could be readily tailored by tuning the polymerization parameters.

16.    Colorimetric Assay for Heterogeneous-Catalyzed Lipase Activity:Enzyme-Regulated Gold Nanoparticle Aggregation

Wei Zhang?(张卫),Yan Tang?(汤燕),Jia Liu?(刘佳),Ling Jiang?(江凌),Wei Huang#(黄维),Feng-Wei Huo*,#,§(霍峰蔚),Danbi Tian*,?(田丹碧)

J. Agric. Food Chem. 2015, 63, 39?42IF=3.107

链接:http://pubs.acs.org/JAFC

Scheme:Schematic Illustration of the Mechanism of

Sensing the Activtiy of Lipase Based on Tween 20-GNPs

   该报道是利用修饰分子采用无毒且具有表面活性功能的材料 T20。它同时具备纳米颗粒保护剂、乳化剂及脂肪酶底物的功效,可使溶液处于均相体系,解决脂肪酶与底物的相界面的问题。脂肪酶的活性可直观察觉,也可进行定量检测,初步试验结果良好。与传统的纳米金比色法一样,纳米金作为传感体系的显色原件,由于电介质的存在会破坏纳米金表面的双电层结构,会导致纳米金在盐溶液中发生聚集为蓝色。该比色检测法的检出限为3.3x10-2mg/mL,与已存在的脂肪酶活检测方法比较,该比色传感器具有诸多优点:成本低廉,检测快捷,可直接肉眼观察,且灵敏度高,选择性好,在高通量检测领域有着广泛的应用前景。

(截止20156月,该文章被引用了1次)

17.    A plasmonic nanosensor for lipase activity based on enzyme-controlled gold nanoparticles growth in situ

Yan Tang(汤燕),a Wei Zhang(张卫),a Jia Liu(刘佳),a Lei Zhang(张磊),b Wei Huang(黄维),c Fengwei Huod (霍峰蔚) and Danbi Tian*(田丹碧)

Nanoscale, 2015,7, 6039-6044IF=6.739

链接http://pubs.rsc.org/en/content/articlelanding/2015/nr/c4nr07579

Scheme:Schematic illustration of the colorimetric lipase assay based

on enzyme-controlled AuNP growth in situ

   该报道是利用具有双亲性质的大分子 T80 不仅作为脂肪酶水解底物还可作为纳米金的保护剂,其分枝基团也可作为合成纳米颗粒的还原剂。以脂肪酶的活性调控合成纳米金颗粒的尺寸以及溶液环境,使 SPR 信号发生变化,其颜色可由肉眼观测,也可进行定量检测好,初步试验结果良好。

18.    Jinyang Hu, Rui Liu, Xiao Cai, Mingliang Shu, Hongjun Zhu, Highly ef?cient and selective probes based on polycyclic aromatic hydrocarbons with trimethylsilylethynyl groups for ?uoride anion detection [J], Tetrahedron, 2015, 71, 3838-3843.

网站链接

http://www.sciencedirect.com/science/article/pii/S0040402015004925

简介

氟离子因其离子半径小,电荷密度大,在生物、医药等领域起着至关重要的作用,因此引起了科研工作者的广泛关注。朱红军教授课题组使用芳香稠环为荧光团,三甲基硅乙炔为识别基团构建的探针可以实现高选择性、高灵敏性的识别氟离子。当氟离子加入到探针溶液中,可以通过肉眼观察到溶液颜色由黄色变为无色,此外制备的纸试纸可以很好的适用于氟离子的检测。

19.    Xiaodong Jin, Chaozhi Liu, Xuemei Wang, Hai Huang, Xueqiong Zhang and Hongjun Zhu, A flavone-based ESIPT fluorescent sensor for detection of N2H4 in aqueous solution and gas state and its imaging in living cells [J], Sensors and Actuators B: Chemical, 2015, 141-149.

网络链接:

http://www.sciencedirect.com/science/article/pii/S0925400515004323

简介:

肼(NH2-NH2)是一种重要的化学试剂,在化学工业中扮演着重要的角色,但其又具有很高的毒性和危险性,对肝、肺、肾脏和神经系统等会造成严重的损害。因此,美国环境保护署(EPA)将其归类为一种潜在的致癌物质,并规定其阈限值低至10 ppb。朱红军课题组以3-羟基黄酮为荧光母体,溴代正丁酸作为特异性反应基团,设计合成了一例新型的具有激发态分子内质子转移(Excited-State Intramolecular Proton TransferESIPT)性质的肼探针,并实现了对水溶液(其检测限为0.15 μM (4.8 ppb))和气态肼的检测(其检测限为0.5%)。另一方面,该探针毒性低、生物兼容性好,能够用于HeLa细胞对肼的荧光成像分析。因而,该探针在揭示肼对生物体病变影响的过程中具有很大的应用前景。

20.    Xiaolin Zhu, Hai Huang, Rui Liu, Xiaodong Jin, Yuhao Li, Danfeng Wang, Qiang Wang and Hongjun Zhu, Aza-boron-diquinomethene complexes bearing N-aryl chromophores: synthesis, crystal structures, tunable photophysics, the protonation effect and their application as pH sensors [J], J. Mater. Chem. C, 2015, 3, 3774-3782.

网络链接

http://pubs.rsc.org/en/content/articlelanding/2015/tc/c4tc02955k

简介:

五个氟硼化合物被设计合成,他们不仅表现出从蓝光到红光的明显的荧光差异,而且具有较高的荧光量子效率。同时,1C化合物对酸碱较为敏感能进一步应用于pH传感器。

21.    Kai Chen, Qi Liu, Jue-Ping Ni, Hong-Jun Zhu,* Yu-Feng Li, and Qiang Wang, Synthesis, insecticidal activities and structureactivity relationship studies of novel anthranilic diamides containing pyridylpyrazole-4-carboxamide [J], Pest Management Science, 2015, DOI: 10.1002/ps.3243

网站链接

http://onlinelibrary.wiley.com/doi/10.1002/ps.3243/abstract

简介

吡唑甲酰胺类化合物由于具有酰胺和吡唑两个高活性基团,从而具有广泛的生物活性。本文以邻氨基苯甲酰胺结构为母体,引入吡啶基吡唑-4-甲酰胺,从而设计合成一类新型邻氨基苯甲酰胺类化合物,并对其进行了生物活性测试及构效关系的研究。生物活性测试结果表明大多数化合物在100 mg L?1浓度下对小菜蛾表现出90 %以上的杀虫活性。此外,本文通过密度泛函理论研究发现,前线分子轨道的研究对构效关系的解释具有指导意义。

 

完整word附件下载:/myEditor/attached/file/20150702/2015070213000459459.docx



地址南京浦口区浦珠南路30号 邮编:210009 电话:025-58139535、9536、9537 邮箱:chem@njtech.edu.cn
版权所有(c)龙8的手机登录网址