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何广科副教授
阅读次数:2920 添加时间:2016/9/7 发布: 管理员
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E-mail: hegk@njtech.edu.cn


学习及工作经历

    *2010/07今,南京工业大学工作

* 2005/12 2009/12,浙江大学,理学博士

2002/09 2005/06,浙江大学,工学硕士

1998/09 2002/07,江苏石油化工学院,学士


研究方向

  炔烃的氟化及硼化反应

主持的科研项目

*  江苏省高校自然科学基金面上项目(12KJB150011)

*  江苏省青年自然科学基金(BK20140937)

3年科研论文

*  Zhu, G.; Qiu, S.; Xi, Y.; Ding, Y.; Zhang D.; Zhang R.; He, G.*; Zhu, H*. (IPr)CuF-catalyzed α-site regiocontrolled trans-hydrofluorination of ynamides Org. Biomol. Chem., 2016, 14, 77467753.

*  He, G.; Qiu, S.; Zhu, G.; Zhang D.; Zhang R.; Zhu, H*. Cu(I)- or Ag(I)-Catalyzed Regio- and Stereocontrolled trans-Hydrofluorination of Ynamides, Org. Lett., 2016, 18, 18561859.

*  Huang, H.; Tang, L.; Yang, Z.; Liu, Q.; Xi, Y.; He, G.*, Zhu, H*. Formation of α-chalcogenyl acrylamides through unprecedented chalcogen-mediated metal-free oxyfunctionalization of ynamides with DMSO as an oxidant, Chem. Commun., 2016, 52, 56055608.

*  Huang, H.; Fan, J.; He, G.*; Yang, Z.; Jin, X.; Liu, Q.; Zhu, H*. Generation of Oxazolidine-2,4-diones Bearing Sulfur-Substituted Quaternary Carbon Atoms by Oxothiolation/Cyclization of Ynamides, Chem. Eur. J. 2016, 22, 25322538.

*  Huang, H.; Zhu, X.; He, G.*; Liu, Q.; Fan, J.; Zhu, H*. Controlled Synthesis of 1,3,5-Oxadiazin-2-ones and Oxazolones through Regioselective Iodocyclization of Ynamides, Org. Lett. 2015, 17, 25102513.

*  He, G.; Chen, S.; Wang, Q.; Huang, H.; Zhang, Q.; Zhang, D.; Zhang, R.; Zhu, H*. Studies on copper(I)-catalyzed highly regio- and stereo-selective hydroboration of alkynamides, Org. Biomol. Chem. 2014, 12, 59455953.

*  He, G.; Zhang, Q.; Huang, H.; Chen, S.; Wang, Q.; Zhang, D.; Zhang, R.; Zhu, H*. Copper(I)-Catalyzed Highly Regio- and Stereoselective Boron AdditionProtonolysis of Alkynamides to give Alkenamides, Eur. J. Org. Chem. 2013, 2013, 69796989.

*  何广科,陈山,马鸿飞,王强,朱红军* 克莱森酯缩合反应中碱性试剂作用的探讨, 化学教育,2014, 35, 5759.




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